Dichlorido(4′-phenyl-2,2′:6′,2′′-terpyridyl)zinc
نویسندگان
چکیده
The title compound, [ZnCl(2)(C(21)H(15)N(3))], was obtained from the reaction of ZnCl(2)·4H(2)O with 4'-phenyl-terpyridine (L) and disodium 2,6-dipicolinate. The Zn(2+) cation is ligated by the N atoms of the tridentate L ligand and two chloride anions, forming a ZnN(3)Cl(2) polyhedron with a distorted trigonal-bipyramidal coordination geometry. In the crystal, nonclassical C-H⋯Cl hydrogen bonds are observed.
منابع مشابه
Dichlorido(4′-ferrocenyl-2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)zinc acetonitrile monosolvate
The title complex, [FeZn(C(5)H(5))Cl(2)(C(20)H(14)N(3))]·CH(3)CN, is composed of one Zn(II) atom, one 4'-ferrocenyl-2,2':6',2''-terpyridine (fctpy) ligand, two Cl atoms and one acetonitrile solvent mol-ecule. The Zn(II) atom is five-coordinated in a trigonal-bipyramidal geometry by the tridentate chelating fctpy ligand and two Cl atoms.
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